355 | 3 | 3 |
下载次数 | 被引频次 | 阅读次数 |
本文对纳米无机氧化物粒子表面的接枝改性作了论述,重点介绍了纳米粒子表面官能团引发的接枝聚合(自由基聚合、阴离子集合、阳离子聚合),并对各种接枝方法以及其发展情况进行了评价。同时对树状接枝进行了简要的介绍。
Abstract:Various reactions that graft polymers onto the surface of inorganic oxide nanoparticles,such as the copolymerization of a monomer with an immobilized double bond at the surface of nanoparticles,the reaction between reactive polymer and the groups of the surface of nanoparticles,the termination of living polymer on the surface of nanoparticles and the graft polymerization initiated by the groups of nanoparticles were reviewed and evaluated briefly.The research of dendrimer was introduced.
[1]TSUBOKAWAN.Graftpolymerizationofvinylmonomersbyperoxyestergroupsintroducedontothesurfaceofinorganicultrafineparticles[J].Polym,1992,17:809-816.
[2]PAIBLER,HAMANNK.Formationofchemicallyboundpolymerlayersonoxidesurfacesandtheirroleincolloidalstability[J].AdvColloidInterfaceSci,1980,13:65-71.
[3]TADAH,SAITOY,HIRATAM,etal.Particlesontheirdispersionstabilityinpoly(dimethylsiloxane)[J].JJpnSocColourMater,1991,64(1):12-16.
[4]TSUBOKAWAN,KOGUREA.Surfacegraftingofpolymersontoinorganicultrafineparticles.reactionoffunctionalpolymerswithacidanhydridegroupsintroducedontoinorganicultrafineparticles[J].JPolymSciPartAPolymChem,1991,29:697-702.
[5]SHIRAIY.Graftingofpolymersontoultrafineinorganicparticlesurface:graftpolymerizationofvinylmonomersinitiatedbythesystemconsistingoftrichloroacetylgroupsonthesurfaceandmolybdenumhexacarbonyl[J].ReactFunctPolym,1997,32(2):153-160.
[6]TIMOTHYV,TIMOTHYE.Preparationofpolymerinorganichybridnanoparticlesusingcontrolledlivingradicalpolymerization[J].PolymPrepr,1999,40(2):354-355.
[7]SCHOMAKERE,ZWARTEVEENA.Synthesisofisotacticpoly(methylmethacrylate)covalentlyboundtomicroparticulatesilica[J].PolymComm,1988,29:158-160.
[8]TSUBOKAWAN,ICHIOKAH.Graftingofdendrimer-likehighlybranchedpolymerontoultrafinesilicasurface[J].ReactFunctPolym,1998,37:75-82.
基本信息:
DOI:
中图分类号:TB383
引用信息:
[1]谢扬,姚素薇,白世河,张卫国,王宏智.纳米无机氧化物粒子表面接枝改性[J].化学工业与工程,2003(06):487-490.
基金信息: